[솔루션] 유기화학 솔루션 (Advanced Organic Synthesis METHODS AND TECHNIQUES 1st …
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II. TheWorkup 175
V. Reactions of Enamines with Acrolein ............... 84
X. Half-EsterificationofaDiol 64
References 67
III. Allylic and Benzylic Bromination with W-Bromosuccinimide 48
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References 157
Appendix 2. Sources of Organic Reagents 161
I. Preparation of the Morpholine Enamine of Cyclohexanone ......... 80
References ....................... 110
VI. Lead Tetraacetate Oxidation of Cycloalkanols 11
II. The Generation of Sodium Acetylide in Tetrahydrofuran 123
X. Dimethyloxosulfonium Methylide in Methylene Insertions 145
IV. The Reaction of Trialkylboranes with Ethyl Bromoacetate ......... 115
15. Structural Isomerizations
VII. The Robinson Annelation Reaction ................ 101
I. Chromium Trioxide Oxidation 3
contents
I. Reduction by Lithium Aluminum Hydride 18
II. Halides from Alcohols and Phenols by Triphenylphosphine Dihalide 46
II. SKELETAL MODIFICATIONS
III. The Reaction of Trialkylboranes with Methyl Vinyl Ketone and Acrolein ..... 114
II. Alkyl Ylides Requiring «-Butyl Lithium .............. 105
VI. Base Catalyzed Rearrangement of 4-Benzoyloxycyclohexanone 131
IV. Trichloroisocyanuric Acid 156
III. Purification of a Mixture of J9-10- and J1(9)-Octalins 37
V. Homogeneous Catalytic Hydrogenation 43
I. Carboxylation of Carbonium Ions 134
I. The Reaction 166
3. Dissolving Metal Reductions
II. Dibromocarbenes 117
I. Reduction by Lithium-Amine 25
설명
III. Purification of the Product 178
Carbon-Carbon Bond Formation
4. Hydroboration
References 30
References 125
V. Bridged Sulfides by Addition of Sulfur Dichloride to Dienes 57
III. Reduction of a,/MJnsaturated Ketones by Lithium-Ammonia 27
II. Acylation of Enamines ................... 81
VI CONTENTS
References 16
III. Reduction with Iridium-Containing Catalysts 22
III. Free Radical Oxidation of an Allylic Position 7
7. Miscellaneous Elimination, Substitution, and Addition Reactions
XI. Substitution on Ferrocene 65
8. The Diels-Alder Reaction
6. The Introduction of Halogen
II. Selective Hydroborations Using Bis(3-methyl-2-butyl)borane (BMB) 35
III. Catalysis by Aluminum Chloride ................ 74
Xl. Acylation of a Cycloalkane: Remote Functionalization 147
I. Benzyl-Containing Ylides .................. 104
5. Catalytic Hydrogenation
[솔루션] 유기화학 솔루션 (Advanced Organic Synthesis METHODS AND TECHNIQUES 1st Edition - RICHARD S. MONSON)
References 24
IV. Boron Trifluoride Catalyzed Hydrolysis of Nitriles 56
IX. Ketalization 63
V. Carboxylations with Magnesium Methyl Carbonate (MMC) ......... 97
V. Stereospecific Synthesis of /ra/w-4-Halocyclohexanols 51
II. Percarboxylic Acids 153
II. Periodate-Permanganate Cleavage of Olefins 5
I. Ketones as Enolates: Car bethoxylation of Cyclic Ketones ......... 87
II. Paracyclophane via a 1,6-Hofmann Elimination 136
1 2 . Reactions of Trialkylbor anes
XII. Demethylation of Aryl Methyl Ethers by Boron Tribromide 66
III. Isomerization of 1-Ethynylcylohexanol: Three Methods 129
IV. Reduction of a,/9-Unsaturated Ketones in Hexamethylphosphoric Triamide . . . . 28
References ....................... 86
13. Carbenes as Intermediates
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1 1 . The Wittig Reaction
VIII. Ring Enlargement with Diazomethane 143
X. Bisdecarboxylation with Lead Tetraacetate 14
IV. The Wittig Reaction Catalyzed by Ethylene Oxide ........... 107
VI. Methylation by Diazomethane 58
XII. The Modified Hunsdiecker Reaction 149
Appendix 1. Examples of Multistep Syntheses 158
III. c/j-4-Hydroxycyclohexanecarboxylic Acid from /?-Hydroxybenzoic Acid 41
CONTENTS IX
VII. Oxymercuration: A Convenient Route to Markovnikov Hydration of Olefins . . . . 60
V. Oxidative Rearrangement of /3-Diketones 130
III. Dehydration of 2-Decalol 56
I. 3,6-Diphenyl-4,5-cyclohexenedicarboxylic Anhydride ........... 71
17. Miscellaneous Preparations
V. Reduction of an a,/?-Unsaturated y-Diketone with Zinc 29
V. Reactions with Cyclopentadiene ................. 77
III. The Generation of Sodium Acetylide via Dimsylsodium 124
III. Enamines as Michael Addition Reagents .............. 82
II. Reduction by Lithium-Ethylenediamine 26
Appendix 3. Introduction to the Techniques of Synthesis
References 150
II. The Wolff-Kishner Reduction 55
I. Derivatives of Adamantane 151
III. Dihalocarbenes from Phenyl(trihalomethyl)mercury Compounds 119
References ....................... 79
I. Acid Catalyzed Rearrangement of Saturated Hydrocarbons 126
VII. Photolytic Conversion of Cyclohexane to Cyclohexanone Oxime 11
References ....................... 115
I. FUNCTIONAL GROUP MODIFICATIONS
VII. Intermolecular Dehydrohalogenation 142
레포트 > 공학,기술계열
V. Baeyer-Villiger Oxidation of Ketones 9
IV. a-Bromination of Ketones and Dehydrobromination 49
IV. Photolytic Isomerization of 1,5-Cyclooctadiene 130
III. Methylsulfinyl Carbanion as a Route to Methyl Ketones .......... 92
I. Carbene Addition by the Zinc-Copper Couple 116
Subject Index 189
II. Esters as Enolates: 1,4-Cyclohexanedione and Meerweins Ester ....... 90
II. Dialkylketones from Trialkylboranes and Carbon Monoxide- Water ...... 112
CONTENTS VlI
16. Elimination, Substitution, and Addition Reactions Resulting in
References 188
References ....................... 103
IV. Phenylcyclopropane from Cinnamaldehyde 139
References 133
IV. Cyclization with Diethyl Malonate ................ 96
Viil CONTENTS
I. Halides from Alcohols by Triphenylphosphine—Carbon Tetrahalide 45
화공, 화학, 솔루션, organic, 유기
I. Hydrogenation over Platinum Catalyst 39
I. Methylenecyclohexane by Pyrolysis of an Amine Oxide 54
II. Mixed Hydride Reduction 20
IV. Reactions of Enamines with j3-Propiolactone ............. 83
순서
9. Enamines as Intermediates
I. Trialkylcarbinols from Trialkylboranes and Carbon Monoxide ........ Ill
V. Conversion of Alkyl Chlorides to Nitriles in DMSO 140
III. Diphenylcyclopropenone from Commercial Dibenzyl Ketone 137
IV. Reduction of Conjugated Alkenes with Chromium (H) Sulfate 23
III. Diazomethane 155
VIII. Oxidation of Ethers to Esters 12
VII. Allenes from 1,1-Dihalocyclopropanes by Methyllithium 132
III. Methylsulfinyl Carbanion in the Generation of Ylides .......... 106
References 44
IV. Generation of Dienes from Diones ................ 75
VI. Alkylation of j3-Ketoesters .................. 99
14. Ethynylation
V. Cyclopropylidene Derivatives via the Wittig Reaction .......... 108
10. Enolate Ions as Intermediates
IX. Conjugate Addition of Grignard Reagents 144
1. Chemical Oxidations
References 38
VIII. Esterification of Tertiary Alcohols 62
XI. Oxidation with Selenium Dioxide 15
II. Reactions with Butadiene .................. 72
IX. Partial Oxidation of an Aliphatic Side Chain 13
References 120
References 52
VI. Photolytic Addition of Formamide to Olefins 141
IV. 3-Isoquinuclidone from/7-Aminobenzoic Acid 42
II. Low-Pressure Hydrogenation of Phenols over Rhodium Catalysts 40
I. Hydroboration of Olefins as a Route to Alcohols 32
2. Hydride and Related Reductions
I. Generation of Sodium Acetylide in Liquid Ammonia 121
II. Photolytic Ring Contraction 127
IV. Epoxidation of Olefins 8
다.
